Altmetric

A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions

File Description SizeFormat 
EJOC_Hydroaminarion_Revision2.pdfFile embargoed until 26 June 2020803.94 kBAdobe PDF    Request a copy
Title: A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions
Authors: Zelenay, B
Munton, P
Tian, X
Diez-Gonzalez, S
Item Type: Journal Article
Abstract: The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalysts was also found active in intermolecular aza‐Michael reactions.
Issue Date: 7-Aug-2019
Date of Acceptance: 26-Jun-2019
URI: http://hdl.handle.net/10044/1/70911
DOI: 10.1002/ejoc.201900701
ISSN: 1099-0690
Publisher: Wiley
Start Page: 4725
End Page: 4730
Journal / Book Title: European Journal of Organic Chemistry
Volume: 2019
Issue: 29
Copyright Statement: © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Zelenay, B. , Munton, P. , Tian, X. and Díez-González, S. (2019), A Commercially Available and User‐Friendly Catalyst for Hydroamination Reactions under Technical Conditions. Eur. J. Org. Chem.. Accepted Author Manuscript. doi:10.1002/ejoc.201900701, which has been published in final form at https://dx.doi.org/10.1002/ejoc.201900701
Sponsor/Funder: The Royal Society
Funder's Grant Number: RG2015 R1
Keywords: Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
Alkynes
Allenes
Copper
Heterocycles
Hydroamination
ANTI-MARKOVNIKOV HYDROAMINATION
AZA-MICHAEL ADDITION
ONE-POT SYNTHESIS
INTRAMOLECULAR HYDROAMINATION
INTERMOLECULAR HYDROAMINATION
ASYMMETRIC-SYNTHESIS
EFFICIENT SYNTHESIS
TERMINAL ALKYNES
AROMATIC-AMINES
N-H
Organic Chemistry
0305 Organic Chemistry
0304 Medicinal and Biomolecular Chemistry
Publication Status: Published
Embargo Date: 2020-06-26
Online Publication Date: 2019-06-26
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



Items in Spiral are protected by copyright, with all rights reserved, unless otherwise indicated.

Creative Commons