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A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions

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Title: A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions
Authors: Zelenay, B
Munton, P
Tian, X
Diez-Gonzalez, S
Item Type: Journal Article
Abstract: The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalysts was also found active in intermolecular aza‐Michael reactions.
Issue Date: 26-Jun-2019
Date of Acceptance: 26-Jun-2019
URI: http://hdl.handle.net/10044/1/70911
DOI: https://dx.doi.org/10.1002/ejoc.201900701
ISSN: 1099-0690
Publisher: Wiley
Journal / Book Title: European Journal of Organic Chemistry
Copyright Statement: © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Zelenay, B. , Munton, P. , Tian, X. and Díez-González, S. (2019), A Commercially Available and User‐Friendly Catalyst for Hydroamination Reactions under Technical Conditions. Eur. J. Org. Chem.. Accepted Author Manuscript. doi:10.1002/ejoc.201900701, which has been published in final form at https://dx.doi.org/10.1002/ejoc.201900701
Sponsor/Funder: The Royal Society
Funder's Grant Number: RG2015 R1
Keywords: Organic Chemistry
0305 Organic Chemistry
0304 Medicinal and Biomolecular Chemistry
Publication Status: Published online
Embargo Date: 2020-06-26
Online Publication Date: 2019-06-26
Appears in Collections:Chemistry
Catalysis and Advanced Materials



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